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Application of a vertex chain operation algorithm on topological analysis of three-dimensional fractured rock masses

Zixin ZHANG, Jia WU, Xin HUANG

《结构与土木工程前沿（英文）》 2017年 第11卷 第2期   页码 187-208 doi: 10.1007/s11709-017-0391-0

摘要： Identifying the morphology of rock blocks is vital to accurate modelling of rock mass structures. This paper applies the concepts of directed edges and vertex chain operations which are typical for block tracing approach to block assembling approach to construct the structure of three-dimensional fractured rock masses. Polygon subtraction and union algorithms that rely merely on vertex chain operation are proposed, which allow a fast and convenient construction of complex faces/loops. Apart from its robustness in dealing with finite discontinuities and complex geometries, the advantages of the current methodology in tackling some challenging issues associated with the morphological analysis of rock blocks are addressed. In particular, the identification of complex blocks with interior voids such as cavity, pit and torus can be readily achieved based on the number and the type of loops. The improved morphology visualization approach can benefit the pre-processing stage when analyzing the stability of rock masses subject to various engineering impacts using the block theory and the discrete element method.

关键词： morphology     block assembling     vertex operation     discontinuities    

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2,5-Dialkoxylphenyl-1,3,4-oxadiazoles as efficient organogelators and their self-assembling property

Zipei SUN,Xuelin DONG,Yan ZHAI,Ziyan Li,Yaodong HUANG

《化学科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 219-224 doi: 10.1007/s11705-014-1418-x

摘要： Four 2,5-dialkoxylphenyl-1,3,4-oxadiazoles are shown to be efficient organogelators. These compounds readily form stable gels in many organic solvents and their gelation property as well as supramolecular structures were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), H nuclear magnetic resonance ( H NMR), and ultraviolet-visible spectroscopy (UV-vis). The results indicate that the gelator molecules self-assemble into gels with elongated fibrous networks and layer structures, and van der Waals interaction is the main driving force.

关键词： 1     3     4-oxadiazoles     organogelator     self-assembly    

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Laser ablation of block copolymers with hydrogen-bonded azobenzene derivatives

Jintang Huang, Youju Huang, Si Wu

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 450-456 doi: 10.1007/s11705-018-1735-6

摘要：

Supramolecular assemblies (PS-b-P4VP(AzoR)) are fabricated by hydrogen-bonding azobenzene derivatives (AzoR) to poly(4-vinyl pyridine) blocks of polystyrene-block-poly(4-vinyl pyridine) (PS-b-P4VP). PS-b-P4VP(AzoR) forms phase separated nanostructures with a period of ~75–105 nm. A second length scale structure with a period of 2 µm is fabricated on phase separated PS-b-P4VP(AzoR) by laser interference ablation. Both the concentration and the substituent of AzoR in PS-b-P4VP(AzoR) affect the laser ablation process. The laser ablation threshold of PS-b-P4VP(AzoR) decreases as the concentration of AzoR increases. In PS-b-P4VP(AzoR) with different substituents (R= CN, H, and CH3), ablation thresholds follow the trend: PS-b-P4VP(AzoCN)<PS-b-P4VP(AzoCH3)<PS-b-P4VP(AzoH). This result indicates that the electron donor group (CH3) and the electron acceptor group (CN) can lower the ablation threshold of PS-b-P4VP(AzoR).

关键词： laser ablation     block copolymers     hydrogen-bond     azobenzene derivatives     supramolecular assembly    

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大直径管片拼装及缺陷处理

程学武,许维青,杨志永

《中国工程科学》 2010年 第12卷 第12期   页码 89-93

摘要：

总结了北京地下直径线工程大直径盾构管片拼装技术，初步分析了大直径盾构钢筋混凝土管片施工过程中的表观破损原因，并对破损管片修补技术进行探讨，提出对拱腰以上、拱腰以下部位管片的不同修补方法，保证了大直径盾构管片的强度及外观质量。

关键词： 大直径盾构     管片     拼装     修补    

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Ductility improvement of GFRP-RC beams using precast confined concrete block in compression zone

《结构与土木工程前沿（英文）》 doi: 10.1007/s11709-023-0968-8

摘要： Fiber-reinforced polymers (FRPs) have received considerable research attention because of their high strength, corrosion resistance, and low weight. However, owing to the lack of ductility in this material and the quasi-brittle behavior of concrete, FRP-reinforced concrete (FRP-RC) beams, even with flexural failure, do not fail in a ductile manner. Because the limited deformation capacity of FRP-RC beams depends on the ductility of their compression zones, the present study proposes using a precast confined concrete block (PCCB) in the compression zone to improve the ductility of the beams. A control beam and four beams with different PCCBs were cast and tested under four-point bending conditions. The control beam failed due to shear, and the PCCBs exhibited different confinements and perforations. The goal was to find an appropriate PCCB for use in the compression zone of the beams, which not only improved the ductility but also changed the failure mode of the beams from shear to flexural. Among the employed blocks, a ductile PCCB with low equivalent compressive strength increased the ductility ratio of the beam to twice that of the control beam. The beam failed in pure flexure with considerable deformation capacity and without significant stiffness reduction.

关键词： ductility     four-point bending test     glass fiber-reinforced polymer     precast confined concrete block    

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Preparation of polysulfone-based block copolymer ultrafiltration membranes by selective swelling and

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 745-754 doi: 10.1007/s11705-021-2038-x

摘要： Selective swelling of block copolymers of polysulfone-b-poly(ethylene glycol) is an emerging strategy to prepare new types of polysulfone ultrafiltration membranes. Herein, we prepared nanoporous polysulfone-b-poly(ethylene glycol) ultrafiltration membranes by selective swelling and further promoted their porosity and ultrafiltration performances by using CaCO3 nanoparticles as the sacrificial nanofillers. Different contents of CaCO3 nanoparticles were doped into the solution of polysulfone-b-poly(ethylene glycol), and thus obtained suspensions were used to prepare both self-supported and bi-layered composite structures. Selective swelling was performed on the obtained block copolymer structures in the solvent pair of ethanol/acetone, producing nanoporous membranes with poly(ethylene glycol) lined along pore walls. The CaCO3 nanoparticles dispersed in polysulfone-b-poly(ethylene glycol) were subsequently etched away by hydrochloric acid and the spaces initially occupied by CaCO3 provided extra pores to the block copolymer layers. The porosity of the membranes was increased with increasing CaCO3 content up to 41%, but further increase in the CaCO3 content led to partial collapse of the membrane. The sacrificial CaCO3 particles provided extra pores and enhanced the connectivity between adjacent pores. Consequently, the membranes prepared under optimized conditions exhibited up to 80% increase in water permeance with slight decrease in rejection compared to neat membranes without the use of sacrificial CaCO3 particles.

关键词： block copolymers     selective swelling     ultrafiltration     CaCO3 nanoparticles     sacrificial nanofillers    

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Comparison between two commercial uranium resins and a uranyl sulphate imprinted resin based on self-assembling

LIU Yaochi, XU Wei, XU Weijian, LIU Hanmao, ZHANG Xiaowen

《化学科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 327-331 doi: 10.1007/s11705-007-0059-8

摘要： In recent years, resins prepared via molecular imprinting technology have received considerable attention owing to their recognition and selective adsorption. This paper deals with the comparative investigation between a uranyl sulphate imprinted ion-exchange based on self-assembling molecular imprinting technology and two kinds of commercial uranium resins (the medium pore resin D263 and strong base resin 201×7). The studies were focused on their kinetics performance, adaptability toward pH, and performance of saturation and elution in laboratory-scale column. The results show that the imprinted ion exchange resin has the fast kinetics, high adaptability toward pH, and good adsorption and elution performance.

关键词： saturation     molecular imprinting     imprinting technology     adaptability     commercial    

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Thermoresponsive block copolymer supported Pt nanocatalysts for base-free aerobic oxidation of 5-hydroxymethyl

《化学科学与工程前沿（英文）》 2021年 第15卷 第6期   页码 1514-1523 doi: 10.1007/s11705-021-2092-4

摘要： A base-free catalytic system for the aerobic oxidation of 5-hydroxymethyl-2-furfural was exploited by using Pt nanoparticles immobilized onto a thermoresponsive poly(acrylamide-co-acrylonitrile)-b-poly(N-vinylimidazole) block copolymer, with an upper critical solution temperature of about 45 °C. The Pt nanocatalysts were well-dispersed and highly active for the base-free oxidation of 5-hydroxymethyl-2-furfural by molecular oxygen in water, affording high yields of 2,5-furandicarboxylic acid (up to>99.9%). The imidazole groups in the block copolymer were conducive to the improvement of catalytic performance. Moreover, the catalysts could be easily separated and recovered based on their thermosensitivity by cooling the reaction system below the upper critical solution temperature. Good stability and reusability were observed over these copolymer-immobilized catalysts with no obvious decrease in catalytic activity in the five consecutive cycles.

关键词： aerobic oxidation     base-free     5-hydroxymethyl-2-furfural     Pt nanoparticle     thermoresponsive block copolymer    

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Molecular dynamics study of water diffusion in an amphiphilic block copolymer with large difference in

Yang Zhou, Phillip Choi

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 440-447 doi: 10.1007/s11705-017-1626-2

摘要： Isothermal-isobaric molecular dynamics simulation was used to study the diffusion mechanism of water in polyurethane- -poly( -isopropyl acrylamide) (PU- -PNIPAm) with a hydrophobic PU/hydrophilic PNIPAm mass ratio of 1.4 to 1 at 298 K and 450 K. Here, the experimental glass transition temperature ( ) of PU is 243 K while that of PNIPAm is 383 K. Different amounts of water up to 15 wt-% were added to PU- -PNIPAm. We were able to reproduce the specific volumes and glass transition temperatures (250 K and 390 K) of PU- -PNIPAm. The computed self-diffusion coefficient of water increased exponentially with increasing water concentration at both temperatures (i.e., following the free volume model of Fujita). It suggested that water diffusion in PU- -PNIPAm depends only on its fractional free volume despite the free volume inhomogeneity. It is noted that at 298 K, PU is rubbery while PNIPAm is glassy. Regardless of temperature, radial distribution functions showed that water formed clusters with sizes in the range of 0.2–0.4 nm in PU- -PNIPAm. At low water concentrations, more clusters were found in the PU domain but at high water concentrations, more in the PNIPAm domain. It is believed that water molecules diffuse as clusters rather than as individual molecules.

关键词： molecular dynamics simulation     amphiphilic block copolymer     free volume     water diffusivity     fujita model    

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Wear mechanism of disc-brake block material for new type of drilling rig

WANG Xinhua, WANG Simin, ZHANG Siwei, WANG Deguo

《机械工程前沿（英文）》 2008年 第3卷 第1期   页码 10-16 doi: 10.1007/s11465-008-0009-2

摘要： To improve friction and wear performance and service life of the disc-brake pair material of a drilling rig, a new type of asbestos-free frictional material with better performance for disc-brake blocks is developed, and its wear mechanism is investigated by friction and wear experiments. Topography and elementary components of the brake block’s wear surface are analyzed by employing SEM and EDAX patterns, revealing its tribological behaviour and wear mechanism. When the frictional temperature is lower, the surface film of the brake block is thinner, dense, smooth with plasticity, and divided into the mixture area, Fe-abundant area, carbon-abundant area and spalling area. The mixture area consists of various constituents of frictional pairs without ploughing and rolling trace. The Fe-abundant area mainly consists of iron and other constituents. The carbon-abundant area is the zone where graphite and organic fibre are comparatively gathered, while the spalling area is the zone where the surface film is spalled and its surface is rough and uneven, with a loose and denuded state. During the period of high frictional temperature, the frictional surface is also divided into the mixture area, Fe-abundant area and spalling area. In this case, the mixture area consists of abrasive dust from friction pairs, and the surface film is distributed with crumby hard granules, exiguous oxide, carbide granules and sheared slender fibre. The Fe-abundant area is mostly an oxide layer of iron with a flaky distribution. Fracture and spalling traces as well as an overlapping structure of multilayer surface films can be easily found on the surface film. The components of the spalling area are basically the same as that of the matrix. At the beginning of wear, the hard peaks from the friction surface of the disc-brake plough on the surface of the brake block. With increasing frictional temperature, the friction surface begins to soften and expand, and oxidized wear occurs at the same time. During the high-temperature wear period, severely influenced by friction heat, obvious softening and plastic flow can be found on the friction surface of the brake block, its anti-shearing ability is weakened, and adhesive wear is intensified. Thermal decomposition of cohesive material in the brake block is simultaneously strengthened, so that constituents shed due to loss of adhesion. Organic fibre is in a flowing state and obviously generates drawing, shearing, carbonization and oxidization. In addition, thermal cracking, thermal oxidization, carbonization and cyclization of organic substances on the surface of brake block can make the friction surface produce pores or cracks, thus fatigue wear occurs.

关键词： asbestos-free frictional     Fracture     cyclization     friction     disc-brake    

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Spatial embedded reinforcement of 20-node block element for analysis PC bridges

LONG Peiheng, DU Xianting, CHEN Weizhen

《结构与土木工程前沿（英文）》 2008年 第2卷 第3期   页码 274-280 doi: 10.1007/s11709-008-0039-1

摘要： The formula for the contribution of prestressed reinforcement on embedded reinforcement element is derived according to the mechanical behavior of PC bridges and the foundational principle of finite element method. Mechanical concept is definite and examples validate the calculation results. Reinforcement element model allows generating a finite element mesh without taking into consideration the layout of reinforcements. Furthermore, the prestressing tendon may pass through the concrete elements in an arbitrary manner. It is an effective approach that the no-node loads are diverted from the tendons to the adjacent concrete elements. A useful arithmetic analysis of the spatial curved tendon PC Bridges is provided.

关键词： arithmetic analysis     calculation     prestressed reinforcement     mechanical     arbitrary    

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A block zero-padding method based on DCFT for L1 parameter estimations in weak signal and high dynamic

Chao WU,Lu-ping XU,Hua ZHANG,Wen-bo ZHAO

《信息与电子工程前沿（英文）》 2015年 第16卷 第9期   页码 796-804 doi: 10.1631/FITEE.1500058

摘要： Weak L1 signal acquisition in a high dynamic environment primarily faces a challenge: the integration peak is negatively influenced by the possible bit sign reversal every 20 ms and the frequency error. The block accumulating semi-coherent integration of correlations (BASIC) is a state-of-the-art method, but calculating the inter-block conjugate products restricts BASIC in a low signal-to-noise ratio (SNR) acquisition. We propose a block zero-padding method based on a discrete chirp-Fourier transform (DCFT) for parameter estimations in weak signal and high dynamic environments. Compared with the conventional receiver architecture that uses closed-loop acquisition and tracking, it is more suitable for open-loop acquisition. The proposed method combines DCFT and block zero-padding. In this way, the post-correlation signal is coherently post-integrated with the bit sequence stripped off, and the high dynamic parameters are precisely estimated using the threshold set based on a false alarm probability. In addition, the detection performance of the proposed method is analyzed. Simulation results show that compared with the BASIC method, the proposed method can precisely detect the high dynamic parameters in lower SNR when the length of the received signal is fixed.

关键词： Threshold detection     Discrete chirp-Fourier transform     Block zero-padding     High dynamic     Weak L1 signal acquisition    

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Repression of CDKN2C caused by PML/RARα binding promotes the proliferation and differentiation block

null

《医学前沿（英文）》 2016年 第10卷 第4期   页码 420-429 doi: 10.1007/s11684-016-0478-3

摘要：

Inappropriate cell proliferation during oncogenesis is often accompanied by inactivation of components involved in the cell cycle machinery. Here, we report that cyclin-dependent kinase inhibitor 2C (CDKN2C) as a member of the cyclin-dependent kinase inhibitors is a target of the PML/RARα oncofusion protein in leukemogenesis of acute promyelocytic leukemia (APL). We found that CDKN2C was markedly downregulated in APL blasts compared with normal promyelocytes. Chromatin immunoprecipitation combined with quantitative polymerase chain reaction demonstrated that PML/RARα directly bound to the CDKN2C promoter in the APL patient-derived cell line NB4. Luciferase assays indicated that PML/RARα inhibited the CDKN2C promoter activity in a dose-dependent manner. Furthermore, all-trans retinoic acid treatment induced CDKN2C expression by releasing the PML/RARα binding on chromatin in NB4 cells. Functional studies showed that ectopic expression of CDKN2C induced a cell cycle arrest at the G0/G1 phase and a partial differentiation in NB4 cells. Finally, the transcriptional regulation of CDKN2C was validated in primary APL patient samples. Collectively, this study highlights the importance of CDKN2C inactivation in the abnormal cell cycle progression and differentiation block of APL cells and may provide new insights into the study of pathogenesis and targeted therapy of APL.

关键词： CDKN2C     acute promyelocytic leukemia     cell cycle arrest     differentiation    

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一个基于混沌的分组密码算法的分析

金晨辉

《中国工程科学》 2001年 第3卷 第6期   页码 75-80

摘要：

“基于混沌的分组密码置换网络的设计”一文提出的一个分组密码算法在已知明文攻击和唯密文攻击下都是很容易被破译的,而且在知道加密变换的条件下,很容易利用分割攻击方法求出该分组密码的密钥。此外,基于Logistic映射的混沌序列的相邻值之间的相互制约性,以及该混沌序列的前若干值对初值的低位比特不敏感。

关键词： 混沌序列     分组密码     移位密码     唯密文攻击     已知明文攻击     分割攻击    

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detection methods for amplify-and-forward relay-aided device-to-device systems with full-rate space-time block Article

Kang-li ZHANG, Cong ZHANG, Fang-lin GU, Jian WANG

《信息与电子工程前沿（英文）》 2017年 第18卷 第6期   页码 788-795 doi: 10.1631/FITEE.1700018

摘要： 中继辅助设备到设备通信是下一代蜂窝网络中一项极具潜力的技术。研究了适用于配置多天线的放大转发中继辅助设备到设备通信系统的不同传输方案。为了解决基于全速率空时块码传输方案的传统最大似然检测算法复杂度高的问题，文中提出两种低复杂度检测方法，分别为采用最大似然合并算法的检测方法和采用联合条件最大似然检测器的检测方法。特别是，所提的基于联合条件最大似然检测器的检测方法，能够通过牺牲一定的存储空间换取较好的并行处理能力。仿真结果表明：针对采用全速率空时块码传输方案提出的两种检测方法，能够获得与传统最大似然检测方法近乎相同的误符号率，但所提检测方法复杂度更低；同时，采用基于全速率空时块码的传输方案比复用传输方案具有更优的误码性能。仿真结果还进一步验证了对所提检测方法的分集增益分析。

关键词： 设备到设备通信；中继；检测；全速率空时块码    

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标题 作者 时间 类型 操作

Application of a vertex chain operation algorithm on topological analysis of three-dimensional fractured rock masses

Zixin ZHANG, Jia WU, Xin HUANG

期刊论文

2,5-Dialkoxylphenyl-1,3,4-oxadiazoles as efficient organogelators and their self-assembling property

Zipei SUN,Xuelin DONG,Yan ZHAI,Ziyan Li,Yaodong HUANG

期刊论文

Laser ablation of block copolymers with hydrogen-bonded azobenzene derivatives

Jintang Huang, Youju Huang, Si Wu

期刊论文

大直径管片拼装及缺陷处理

程学武,许维青,杨志永

期刊论文

Ductility improvement of GFRP-RC beams using precast confined concrete block in compression zone

期刊论文

Preparation of polysulfone-based block copolymer ultrafiltration membranes by selective swelling and

期刊论文

Comparison between two commercial uranium resins and a uranyl sulphate imprinted resin based on self-assembling

LIU Yaochi, XU Wei, XU Weijian, LIU Hanmao, ZHANG Xiaowen

期刊论文

Thermoresponsive block copolymer supported Pt nanocatalysts for base-free aerobic oxidation of 5-hydroxymethyl

期刊论文

Molecular dynamics study of water diffusion in an amphiphilic block copolymer with large difference in

Yang Zhou, Phillip Choi

期刊论文

Wear mechanism of disc-brake block material for new type of drilling rig

WANG Xinhua, WANG Simin, ZHANG Siwei, WANG Deguo

期刊论文

Spatial embedded reinforcement of 20-node block element for analysis PC bridges

LONG Peiheng, DU Xianting, CHEN Weizhen

期刊论文

A block zero-padding method based on DCFT for L1 parameter estimations in weak signal and high dynamic

Chao WU,Lu-ping XU,Hua ZHANG,Wen-bo ZHAO

期刊论文

Repression of CDKN2C caused by PML/RARα binding promotes the proliferation and differentiation block

null

期刊论文

一个基于混沌的分组密码算法的分析

金晨辉

期刊论文

detection methods for amplify-and-forward relay-aided device-to-device systems with full-rate space-time block

Kang-li ZHANG, Cong ZHANG, Fang-lin GU, Jian WANG

期刊论文